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It has been reported that grain growth is especially rapid in the early stages of sintering. In [], densification and grain sizes in a nanosize WC – Co powder were studied depending on the duration of liquid-phase sintering (5, 15, 30, 60, 90, 180 and 360 min) and on its temperature (1630, 1670, 1710, 1750 K).The grain size in the samples increased …
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The microstructure of WC-xCo (x=0.5-20 wt.%) is studied for a range of carbide-to-binder ratios and for various sintering temperatures. For 0.5≤Co≤5 wt.%, …
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In this study, the WC–Co cemented carbides with different Co contents (12–32 wt%) were prepared by optimized SLM processes for comparative investigation …
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1. Introduction. Cobalt is the most widely used binder metal in cemented carbides because of the excellent interface properties exhibited by the WC–Co system [1].However, one of the major trends in hardmetal industry is focused on finding new binder phases to replace cobalt [2], [3].Main reasons for this are the toxicity of cobalt, the …
Fig. 1 schematically shows the W-Co-Re-C phase diagram at 9 wt% Re + 6 wt% Co, which was elaborated based on the results obtained in the literature (Ref. [6]) and experimental results of the present work, in comparison with the corresponding WC-Co diagram at 10 wt% Co redrawn from Ref. [13].When taking into account that Re has a …
Functionally graded WC-Co (FG WC-Co) offers enhanced property combinations and superior engineering performance compared to conventional …
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The microstructure of Co and WC powders are shown in Fig. 1. The weight percent of Co powder is varied from 0.5% to 20% by adjusting the Co:WC ratio in the ink. For each 1 cm 3 of Co+WC powder blend, 0.44 g PS, 0.1 g DBP, 0.6 g EGBE, and 9 ml DCM are used. Wet milling is carried out in a WC milling vial for 10 min to mix metal …
FG WC-Co materials with a wide range of thicknesses (ranging from <20 μm to over 2000 μm) were successfully produced for various WC-Co grades (with Co contents from 6 to 16 wt%, WC grain sizes from 0.7 to 2 μm, and grain growth inhibitor additions from 0 to 0.5 wt%). This wide range of FG WC-Co is suitable for the majority of WC-Co tool ...
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The high temperature oxidation behavior of WC-Co samples has been investigated. The oxidation rate of WC-Co was found to increase rapidly with temperature above 600 °C and with the oxygen content of the atmosphere. Increasing the Co content led to an improvement in the oxidation behavior. In all cases, only WO 3 and CoWO 4 …
2.1. Materials and sample preparation. The materials used for the grinding experiments were various kinds of liquid phase sintered hard metals with WC grain sizes of 3, 5, 10 and 20 μm and cobalt contents of 6, 10 and 20 wt.% (Boart Longyear), which lead in principle to 12 different kinds of Co–WCs.
Tungsten carbide-cobalt is an alloy of hard, ceramic tungsten carbide and the ductile cobalt, often known as cemented carbide. The material is a metal matrix composite, in which cobalt particles are ambedded in a tungsten carbide matrix. The tungsten carbide can form as WC or WC 2, depending on synthesis conditions.
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The polished cross-sections of the WC-Co, WC-Co-2ND, and WC-Co-10ND samples had a surface roughness of ~11.5–12.5 nm, as determined by atomic force microscopy (AFM).
The Young's modulus E is shown as a function of temperature for HM grades with a variation in Co content in Fig. 3 a) and in WC grain size in b), respectively.At RT E depends solely on the Co content as it decreases with increasing Co content, see Fig. 3 a), whereas it is independent of the WC grain size, see Fig. 3 b). The observed values of E …
Tungsten carbide cobalt (WC-Co) matrix nanocomposites reinforced with varying amounts of ND (2 – 10 vol.%) were synthesized here by spark plasma sintering.
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2.1. Materials and sample preparation. The materials used for the grinding experiments were various kinds of liquid phase sintered hard metals with WC grain sizes …
6. Discussion. In WC–Co machining by EDM, the high electrical conductivity of Co with 1320 °C melting and 2700 °C evaporation points are significant, whereas WC with 2800 °C melting and 6000 °C evaporation points, has very low electrical conductivity as shown in Table 1. Therefore, when a single discharge takes place, only the melting and ...
Ultrafine/nano WC–Co cemented carbide is widely used because of its high hardness, strength, toughness, and other comprehensive properties. However, WC grain growth during preparation is a persistent issue that hinders the development of this type of cemented carbide. In this context, we review current research on the preparation of …
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WC–Co cemented carbides, well-known as the conventional tooling materials, have not been successfully produced by one step additive manufacturing processes such as selective laser melting (SLM) yet. The microstructure evolution as well as WC grain growth behavior has rarely been investigated in detail during SLM process. In this study, …
Yang et al. investigated the effects of fine WC contents on the microstructure and mechanical properties of inhomogeneous WC-(fine WC–Co) cemented carbides. …
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